Ok, iron makes more sense.
The brown/red color matches iron, not copper. Copper will be turquoise or black.
Ascorbic acid should work when applied directly.
BBs look like copper, but are usually steel with a copper coating. To confirm, see if the BBs stick to a magnet.
Copper does not oxidize easily and typically won't stain from having a copper item sit in contact with the floor for short periods of time under normal conditions.
Lots of brushing should help.