Doesn't matter as long as you stay above minimum.
Compare.
Let's say minimum is 4 and daily use is 2.5.
In the morning you test at 4.5, add to get to 7. By bedtime, it's down to 4.5 and you lose none to the sun at night. Next morning, 4.5.
In the evening, you test at 4.5. You add to get to 7 and go to bed. In the morning, it;s 7. By evening it's down to 4.5.
Either way you're at 7 before it gets serious solar losses, and it never dipped below minimum. It's a wash. Whichever works out more convenient is best, because it's more likely to get done.