The only way I have ever been able to get rid of black algae is drain the pool, pressure wash, spray full strength chlorine on the dry walls. I had a bad case of black algae then my salt chlorinator broke and the walls were coated with yellow algae for a few days. I shocked the pool, brushed walls, ran the robot and filter. The yellow was dead and black was 99% gone. I had been working on the black for months with zero success until the yellow came and ate the black?