There's a certain bacteria that eats CYA and leaves ammonia behind. Think of it like yeast. Yeast takes sugar and turns it into carbon dioxide. This takes CYA and turns it into ammonia. Adding more CYA will just create more ammonia. It takes approximately ten times as much bleach to neutralize ammonia. So why make a tough job even harder? Kill the bacteria while neutralizing the ammonia by adding bleach. When it stops disappearing almost instantly and turning into combined chloramines, you've finished. Then you can proceed.