Try a Vitamin C tablet first. Plain Vitamin C, the cheapest you can find at the drug store or what you can beg from a health-fiend friend or relative. If you get this
It's metal.
If that doesn't lift it, then set a trichlor tablet or puck on the spot for about five minutes. If it lightens, it's probably organics and time and high levels of oxidizers (bleach or whatever you use in a bromine system) should fade it.
The good news is, if it's metals and since it's a spa, you can afford to drain and refill, so you can treat the metal staining and then replace the water and be rid of it for keeps
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