This chart is a bit over my head to understand, sorry but thanks for trying. All I know is my test kit has a test for FC and that is my only gage on if my chlorine is balanced. I also understand PH is very inportant player with the effectivness of Chlorine too. I know that Chlorine is a gas and when combined with water forms an acid abreviated in chemistry terms as HOCI the active componet that does the sanitizing. Household bleach is less potent than pool Chlorine at much higher concentrations to water. The recommened concentration limits for swimming is the same as for drinking city water 4 ppm. Public pools and spas have higher limits. High concentrations of Chlorine are dangerous. I sometimes smell the off gasing fron chlorine standing by my pool and I'm told that actually means you don't have enough chlorine in the pool; I would think that means you have too much. If your logic is the CYA is somehow sequestering it and not available therefore the limits are inaccurate, the thing is the chlorine is in the water and so are you
Good morning. I've been away from your thread for a while, but this particular conversation caught my eye for a few reasons, so I'd like to address them. First, I agree, that chart noted above is can be confusing and the FC/CYA relationship doesn't need to be. Not really sure why we're getting that much in depth here, but unless someone is a scientist, we simply realize (and can prove) that the FC needs to be balanced to the CYA per the
FC/CYA Levels for optimal pool care (algae prevention and waste elimination). That's it, plain & simple. I suspect you've seen that here already. The only difference is how much FC to administer and maintain depending on the CYA level and/or if the pool water is sick or healthy (SLAM or not). Anything beyond that is a discussion in the Deep End forum for the science geeks IMO.
Outside of TFP you may hear the pH plays a role in FC effectiveness. To a very small degree perhaps, but it's not applicable here at TFP. As long as the pH is anywhere between 7.2-7.8, that so-called relationship doesn't even need to be addressed. There is no major interaction or influence between one or the other. Again, something for the Deep End perhaps, but not the regular TFP pool owner.
The recommended concentration limits for swimming is the same as for drinking city water 4 ppm. Public pools and spas have higher limits. High concentrations of Chlorine are dangerous.
Drinking water and pool water cannot be compared. Two totally different scenarios and chlorination requirements. Same goes for residential versus commercial/public pools. Completely different methods of water management. Chlorine is not dangerous unless it is misused, much like any other chemical. We can't speak for the rest of the country or industrial applications, but what we can confirm is that the
FC/CYA Levels was developed by scientists affiliated with TFP over several years to not only ensure water clarity, but safety - both physical and biological.
I sometimes smell the off gasing fron chlorine standing by my pool and I'm told that actually means you don't have enough chlorine in the pool;
That is the combined chlorines being oxidized. Basically the trash/residual chlorine oxidizing from the water. You may notice that smell at public pools quite often. Nothing is wrong, and it doesn't mean you need to arbitrarily add more chlorine, it just means the free chlorine is doing its job. It is attacking the organic materials and the trash chlorine (CC) are being removed.
In summary, not really sure why this particular discussion went so much into depth or across a few different scenarios, but for the average TFP homeowner with a pool, TFP is all about simplicity. Now if you or anyone else has a strong concern about chemical relationships and wants to know more, feel free to visit the Deep End forum where they get WAY into the weeds about just about every chemical and molecular relationship you can think of. Way over my head. If you would like additional info to that degree and can't find the answer there by searching on your own, you are welcome to start a thread in that sub-forum and one of our science experts will gladly break it all down for you.
I hope that helps in some way.