Because humans are weird and very fragile. If the PH is a little different (roughly .5) than our own, it hurts our eyes too. We are roughly 9000 ppm salt. A traditional chlorine pool will be up to 1k ppm and it feels harsher. Most people start to feel it around 2k, and by 3k it almost feels silky smooth.
Ironically, too much is uncomfortable too. I was *thisclose* to not going salt because of living by the ocean. At 30k ppm, it's very uncomfortable after a while. Lips get swollen and cracked. You can't drink enough to quench your thirst and your eyes sting for hours. Also, if you dry up fast enough, you can have an actual salty dust like coating in places. When I finally hopped in my salt pool @ 10% the salinity of the ocean, it felt amazing with *none of that*. Couldn't even taste it.