Hello- we have had our pool pebble sheened about 20 years ago. Regular maintenance, have drained the pool many times (when the pool was seriously green with Algae) and have never had a problem… until now. We have the same issue of splotches all over the bottom of the pool- we drained scrubbed power washed and refilled. Have not put chemicals in the water yet. We now have the same splotches as seen in your pictures. I don’t think it’s the pebble sheen. Maybe something added to the city water? This has never happened in the twenty years of having our pool.