Best way to minimize it is to run your spillway the minimum necessary. A couple times a day for 30 minutes or so is all that is needed for sanitation, typically. Then run it when you want to show off the feature. You have the automation to manage that.
Otherwise, no. Rough stone spillways will always exacerbate the calcium scale as you have more surface area for evaporation. Maintaining a slightly negative CSI will help, but not eliminate the issue.