Phosphates.....are they worth removing??

As I plan upon a similar experiment upon opening and balancing, I am very curious to not only see your results, Matt, but to also see how you log them in order to provide consistency of "population statistics". The protocol would be important for meaningful data collection. Thanks.
 
Would it add anything to draw off say a 100 litres and check for growth over five days in the absence of any FC additions? Just a thought

Lol. I can answer this one. At 25,000 ppb, with FC at 4 or 5 for cya of 35-ish, pool water poured into my fountain will go green by the morning of the third day, which is about how long it takes for the FC to wane. Ask me how I know ;)
 
Lol. I can answer this one. At 25,000 ppb, with FC at 4 or 5 for cya of 35-ish, pool water poured into my fountain will go green by the morning of the third day, which is about how long it takes for the FC to wane. Ask me how I know ;)

I give up. Lol - Call me old fashioned but I don't think laughing at anyone is very funny.

At 25,000ppb PO4 and insufficient FC you'll get green water. At 1000ppb PO4 and insufficient FC you'll get green water. At 100ppb and insufficient FC you'll get green water. And you can have green water in the abcences of FC even at a concentration of 0ppb of PO4. At 0ppb PO4 green water will persist unless a sanitiser is introduced. A sanitiser will not remove PO4 and PO4 is not a sanitiser.
 
In an effort to post meaningful information, here is a research Master's thesis from 2014 out of Cranfield University (UK) that has LOTS of great data and references on nutrient control in NSPs (natural swimming pools) -

https://dspace.lib.cranfield.ac.uk/bitstream/1826/9693/1/Mariner_R_2015.pdf

Now, before anyone freaks out, this is NOT an endorsement of NSPs in anyway. I find the whole idea of bathing in a NSP to be, well, disgusting. You'll never catch me ever swimming in lakes because I think they are gross for the most part ... give me a properly chlorinated swimming pool any day of the week.

The reason why I posted this is because it has some interesting science on the control of nutrient levels in swimming water. Since NSPs, by definition, do not use halogen-based disinfectants (or any disinfectants for that matter), they rely solely on the control of water chemistry, nutrient levels and biological content through the use of novel chemisorptive materials (clays, etc), coagulation with physical filtration and active biofilms to control organic waste. The major discussion in the research thesis on phosphorous control is to find the right kind of filtration materials to keep the phosphorous levels below inhibition levels at roughly 10ppb or less. While this research is focused on attempting to get phosphate levels well below their growth-limiting concentrations, it's interesting to read about the various ways in which the local environment can recycle and reuse phosphorous as was mentioned by AUSpool in a few posts back.

I'll have to comb through some of the references in this thesis to see if there's any information available on phosphorous nutrient levels in the ranges of interest for swimming pools that feature active sanitation. It was never the intent of my own experiment to get to a truly nutrient limiting growth concentration of phosphates (oligotrophic conditions) but to see what impact a low nutrient environment would have (10ppb < [PO4] < 1000ppb) as we know that phosphate concentrations above a certain level (somewhere in the 1000ppb range) are pretty much not considered to be a limiting factor on growth rates.

Please read for yourselves when you have the time.

Matt
 
Swampwoman - sorry, just ignore me. Your response though is exactly what I should have expected as I think anyone would agree that at just about any PO4 concentration once the FC/CYA ratio gets too low we'll end up with an algae bloom. My pool has a PO4 conc. of ~0-30ppb and I'm sure that if I turned off the chlorinator I would have an algae bloom. Just to satisfy my own curiosity I've drawn off some water into a large glass vase and sat it beside the pool. But I can't help think that there is more going on here than first thought and I'm starting to think that there is no simple or direct relationship between phosphorus and the FC/CYA ratio.

Matt, that thesis is a good find, I'm not in the NSP camp either but I love all the references. Its much better than the 'Phosphates - Myths and Facts' article, there's a bit in there that I disagree with but I do agree that there are many pool owners or operators that worry too much about phosphates and would do better to concentrate on the FC and/or the FC/CYA ratio and just enjoy the pool.

Many years ago the accepted phosphate level in a marine aquarium was 0ppm. With the introduction of a ferric oxide phosphate medium absolute zero became achievable but may hobbyists started to report of coral bleaching events. The phosphate target has since changed to undetectable but a figure of 0.03ppm was adopted where below that zooxanthellae stress would be a problem and above it a shift in population densities toward nuisance species would occur. Nutrient control via bio mass removal is a more recent technique used in marine aquariums where a carbon source is added to encourage a bacterial or algae bloom that is removed via protein skimming. Adding a nutrient to remove nutrients took a while for me to accept.

Going back to my 100 litre experiment, at a concentration of 100ppb PO4 there is a given mass weight of available P, I'm not going to attempt to quantify it but I'll call it 1 gram for convenience. In a 30,000L pool that would be 100 grams and in a lake it would be much much more. In the 100 litres the available phosphate could easily be used and become limiting during a active algae bloom. In the pool there is a good chance that the available P will not become limiting and as the concentration increases the chances of available P no longer being limiting increases.

I read somewhere from this thread a comment that said something like 'adding any more phosphate will not have any more affect on growth rates', which got me thinking. Assuming there is an agal bloom and available P is not limiting any one of the other growth factors could become limiting as the bloom slows. Given that light and temperature would be the same as the day before I would rule those out which leaves nitrogen or carbon as the two contenders for limiting the growth. Initially I wouldn't suspect carbon as being limiting but I'm not so sure. Bacillus sp. are feed with glycerol as a carbon source for the commercial preparation of bacteria enzymes presumably because carbon becomes a limiting growth factor. For me it makes a direct relationship between phosphate and the FC/CYA ratio a lot more difficult.
 
^From past discussion, my understanding had been that a high PO4 level like mine is more reactive in that without FC ratio, algae quickly forms. That's what I meant about my fountain. When using pool water, it seems to form algae faster (eg as soon as the FC drops) whereas with well water without FC it seems to take longer. (Eg 3-4 full days.)

If i could ship you some of my high PO4 water to test alongside your sample, my expectation would be that each without FC to the 7.5% ratio would develop visible algae at different rates -- mine first ;)

But once each "took off" if there were adequate nutrient levels, even though mine is dramatically higher, each could still only reproduce at the guideline of 3-8 hours. The point ChemGeek had made long ago is that there are other limiting factors on the reproduction capability beyond nutrient.

Therefore, high PO4 water is more reactive for sure, but ultimately even low PO4 water can support the algae life cycle once started, at which point growth is more or less equalized by the other limiting factors on the reproductive cycle.

Which is pretty much why in each condition the collective surmised that if you maintain the FC:CYA ratio, it didn't make much difference whether your PO4 was 1,000 or 10,000. Nobody envisioned, like aquaria, getting to zero ;) I don't think that's easily achievable, or "trouble free."

However, if this "reactive" PO4-laden water also has the potential to foul an swg plate, reducing its efficacy, or to make running the swg at a lower FC:cya ratio less forgiving, then its worth a look.
 
This may have been addressed earlier but if you lower the phosphates in order to minimize the FC needed, is the lower FC compromising the disinfecting ability against bacteria and other potential threats? Most of this thread is over my head, but I am curious enough to keep reading, lol.
 
This may have been addressed earlier but if you lower the phosphates in order to minimize the FC needed, is the lower FC compromising the disinfecting ability against bacteria and other potential threats? Most of this thread is over my head, but I am curious enough to keep reading, lol.

No. Even at a lower FC/CYA ratio, there should still be sufficient sanitizing power to kill bacteria. However, properly managed residential swimming pools don't generally have high bacterial loads to begin with and so it's only a concern if lots of sick people are swimming in a pool. Those bacterial types that are hard for chlorine to kill (cryptosporidium, etc) would be difficult to kill at any FC/CYA ratio but are typically rare to find in pool water.

Where one might see a change in water quality is in CC measurements. The oxidation of organic compounds is directly proportional to the concentration of hypochlorous acid in pool water. Since a lower FC/CYA ratio means a lower concentration of HOCl, the rate of oxidation will be lower. Again though, outdoor residential pools tend to be low bather-load and exposed to plenty of UV light so one may or may not detect CC differences. Even at a 3.5% ratio there would still be sufficient amount of chlorine around to oxidize bather waste, it may just take a little longer.
 
Swampwoman, I did read your post, so it wasn't in vain. It's nothing to do with you, but I very much dislike their approach in addressing this with the general public because it is misleading and unclear. If the makers of SWG systems are going to say Phophates are a problem then they need to spell out why. We see this on the forum more and more where users have just been told phosphates are the problem when a user is having trouble customer service can't solve, or explain. It's just easy to blame phosphates, and we are left to deal with some of those users questions.

There is simply way too little information being given, and it seems like another crutch for them to lean on.

As an aside, I've tested my phosphate levels and found 515 PPB as the number I'm settling on as an average of three tests, but I plan on no action to reduce them. I'm slightly curious where I should theoretically get into trouble with my FC/Cya ratios, but I'm honestly not too worried about it. Your 25000 PPB ought to give anyone confidence, but we've seen members with >3000 manage without undue trouble while maintaining normal FC/Cya ratios.

If anything, I'm curious how much under the suggested ratios I can manage without running into trouble. I may try running it less this summer just to find out.
 

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If anything, I'm curious how much under the suggested ratios I can manage without running into trouble. I may try running it less this summer just to find out.

Pre TFP I've had a few low FC/CYA ratios but the lowest was just 2.2% (FC 0.8, CYA 35, CC 0.1 PO4 0ppb) until this summer the pool has always been cold with no one ever really swimming in it, a glorified water feature really. I've never had an algae issue and my notes indicate that the FC was back up to 2ppm the very next day.

Out of interest I now manage a second pool, lucky me, concrete with a SWCG that is not self cleaning. Between cell cleaning the FC/CYA ratio will slowly decrease. I target a FC of 5ppm and CYA of 70ppm (PO4 = 0ppm), a FC/CYA ratio of 7.1%. I cleaned the cell yesterday and didn't think to get any readings - oops, running late for school pickup on the first day back. When I took charge of the pool the cell was badly scaled with FC at 2.3ppm, CC at 5.8ppm, CYA at 20ppm and a FC/CYA ratio of 11.5%. :eek: Assuming that at worst it now gets to as low as 3ppm that's still a FC/CYA ratio of 4.3% so it will constantly cycle between ~7 and 4.5%.
 
As an aside, I've tested my phosphate levels and found 515 PPB as the number I'm settling on as an average of three tests, but I plan on no action to reduce them. I'm slightly curious where I should theoretically get into trouble with my FC/Cya ratios, but I'm honestly not too worried about it. Your 25000 PPB ought to give anyone confidence, but we've seen members with >3000 manage without undue trouble while maintaining normal FC/Cya ratios.

If anything, I'm curious how much under the suggested ratios I can manage without running into trouble. I may try running it less this summer just to find out.

Hey Patrick,

Definitely keep us updated on this goes for you! Having another data point would be great. What FC/CYA ratio do you typically run at?

PS - 515ppb.....hmmm....looks like someone took a water sample to work for testing :tongue:


Pre TFP I've had a few low FC/CYA ratios but the lowest was just 2.2% (FC 0.8, CYA 35, CC 0.1 PO4 0ppb) until this summer the pool has always been cold with no one ever really swimming in it, a glorified water feature really. I've never had an algae issue and my notes indicate that the FC was back up to 2ppm the very next day.

Out of interest I now manage a second pool, lucky me, concrete with a SWCG that is not self cleaning. Between cell cleaning the FC/CYA ratio will slowly decrease. I target a FC of 5ppm and CYA of 70ppm (PO4 = 0ppm), a FC/CYA ratio of 7.1%. I cleaned the cell yesterday and didn't think to get any readings - oops, running late for school pickup on the first day back. When I took charge of the pool the cell was badly scaled with FC at 2.3ppm, CC at 5.8ppm, CYA at 20ppm and a FC/CYA ratio of 11.5%. :eek: Assuming that at worst it now gets to as low as 3ppm that's still a FC/CYA ratio of 4.3% so it will constantly cycle between ~7 and 4.5%.

AUSpool,

It's very interesting that you ran at 2.2%. What do you define as a "cold pool"?

To All,

In general, I'd like to reiterate that the point of phosphate removal is NOT to act as a sanitizer. One could, with a lot of money spent, try to make their pool completely oligotrophic and starve the flora & fauna to death. But that is just not a practical approach for residential pool care. The point of phosphate removal is to make the water "less reactive" to algae so that a pool owner can have a larger buffer against developing a green swamp. By "less reactive" we mean that, even if algae finds it's way into the water, the rate of growth is so restricted that the CT kill rate of chlorine is more than sufficient to keep it in check. That CT kill rate is proportional to the FC/CYA ratio, as the FC/CYA ratio is directly proportional to the amount of hypochlorous acid in the pool water. One only needs to maintain a CT kill rate that is greater than the algae reproduction rate in order to keep a pool clean. This is why pools that are deficient in nutrients or have secondary sanitizers in them (for example, borates or algaecides) can sometimes operate at lower FC/CYA ratios; there's nothing controversial or surprising about that. The question, of course, comes down to one of cost & complexity and what the pool owner is willing to tolerate in terms of water management.

I'm a big believer in the idea that you need to be able to accurately measure any chemical you put into your water in order to understand what effect it is having. This is why I'm generally against the use of algaecides, even Polyquat-60, because they basically operate on the "dose & pray" philosophy - dose the water with the chemical based on nothing more than pool volume and intervals of maintenance dosing and "wait & see" if it works? That to me, as an engineer, is not at all acceptable. The problem is there are methods and test kits available for measuring quaternary ammonium algaecide concentrations but they are expensive and, generally speaking, the tests are not easy to perform. So, in that case, the use of algaecides represents a cost in terms of both time and money that I think is not worth it.

On the other hand, at least in my pool, adding borates once per season (that's all it takes really) and lowering phosphates once per season, does not represent a huge cost in terms of either time or money. So, if I can deploy those two secondary methods and get reasonably good results, then they are worth it. What constitutes "reasonably good results" would be less pump run time and/or SWG output because that is the primary measure of how much FC I add to my pool. If my results wind up being a 5% difference in pump run time over the course of the season, then that's a negative result. If my pump run time is cut in half, then that's a very meaningful positive result.

So, only time will tell.....

And, as always, if you are someone who just likes a simple approach and could care less about about playing amateur pool chemist, then keeping your FC/CYA ratio at TFP guidelines is more than sufficient to operate a clean and trouble-free pool.
 
So that I keep good records, I'll let you know where my water chemistry is at and how I plan to manage it. As of today, these are my water chemistry results:

FC: 7.6ppm
CC: 0ppm
pH: 7.8
TA: 70ppm
CH: 850ppm
CYA: 70ppm
: 44ppm
[Cl-] : 3800ppm

temp = 70F

So, I've added 20oz of MA to bring my pH down to 7.6. I have also added roughly 6 lbs of boric acid to push my borates over the 50ppm mark. I will retest borates again in a few days to confirm my exact concentration. My FC is kind of high right now because I have been running my pumps a little more than usual lately and there have been a few cloudy/rainy days so I'm sure the UV loss was a lot lower. I will plan on increasing my CYA to 80ppm, probably tomorrow. I only need to add 2 lbs so I might just sprinkle it over the surface of the water and brush like mad (Note to New TFP'ers : broadcasting CYA over the water IS NOT the recommended method...).

As for my FC management, I will adjust my SWG and pump output to target an FC of ~3 to 3.5ppm. That will put me at roughly a 3.75% FC/CYA ratio or roughly 25% lower than last summer when I tried to target a 5% ratio. Admittedly, last summer, I had a tendency to run my FC higher so I was probably running more like a 6% ratio on average.

We'll see how it goes....
 
Aqua magazine just put out an article suggesting high Phosphates can lead to SWG cell failure...

Failing Salt Generators: The Phosphate Connection - AQUA Magazine

Any truth to this?

EDIT: oops I didn't read a few posts above me. Leaving the link for now..

Unclear at best. Chem geek derived a formula for predicting calcium phosphate scale and you have to have EXTREMELY HIGH phosphate levels for there to be an issue. Only people that have a high use rate of phosphonate based sequestrants with very little fresh water exchange would be possibly affected.

I don't think the evidence is very strong at the moment and swampwoman's conversation with an SWG manufacturer seemed to indicate that they can not (or will not) specify a "dangerous" phosphate level for warranty purposes so it doesn't seem to be clear at all if it's a factor.
 
Unclear at best. Chem geek derived a formula for predicting calcium phosphate scale and you have to have EXTREMELY HIGH phosphate levels for there to be an issue. Only people that have a high use rate of phosphonate based sequestrants with very little fresh water exchange would be possibly affected.

I don't think the evidence is very strong at the moment and swampwoman's conversation with an SWG manufacturer seemed to indicate that they can not (or will not) specify a "dangerous" phosphate level for warranty purposes so it doesn't seem to be clear at all if it's a factor.
So, forgive me you've already explained this (a lot to absorb in this thread), is the purpose of your phosphate removal experiment to achieve a lower FC/CYA ratio?

Aside: It looks like chemgeek isn't posting here anymore :-( I always really enjoyed his posts (your's too). I hope all as well with him.
 
So, forgive me you've already explained this (a lot to absorb in this thread), is the purpose of your phosphate removal experiment to achieve a lower FC/CYA ratio?

Precisely. Standard TFP FC/CYA ratio for manually dosed pools is 7.5%. For pools with SWGs, the ratio is 5%. For chlorinated pools with borates added and phosphates removed...??? (Unknown)

Like Captain Kirk, I'm heading for "The Undiscovered Country" (admittedly not the best Star Trek movie, but definitely not the worst...)
 
Yup, I am aiming for a lower FC/CYA ratio in my non-SWG, (borates added), pool. I feel confident in my ability to fix any issues that may arise. I don't work during most of the swim season here so I have time to fiddle and I look forward to participating in data collection which could help further advance our knowledge of the finer points of pool chemistry.
 
AUSpool,

It's very interesting that you ran at 2.2%. What do you define as a "cold pool"?

Pre solar heating cold for us was 26degC (79F), it would only go over that with several hot cloudless days.

I can't say that I ran it at 2.2%, that was just a low point back in February 2013. I tried to run at FC:3/CYA:50, 4%. At 3.75% I think you'll be safe but do you have a figure in mind where you think it may go pear shaped?

The old hand book, AquaChex by Hach, that I lived by recommended a FC range of 1-3ppm and a CYA range of 30-50ppm which puts the extremes of FC/CYA ratios at 2 - 10%.
 

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