Hey, Again! We don't shock pools, that wouldn't be nice (LOL). We SLAM. Use these instructions, print them out, read them 3 times! Link-->
SLAM Process
I would lower your pH to 7.2...add the right amount of muriatic and keep the pump running (test it to confirm you got to 7.2 about 30 minutes after the addition), then SLAM!
You can work on the TA reduction after the slam...better to clean up that spa with a slam first.
Ignore the MSP. Not sure what that is, can you post a pic of the container and the ingredient list? Maybe you meant MPS?..."MPS" stands for monopersulfate as in the chemical potassium monopersulfate. It is also called non-chlorine shock. It is an oxidizer and by itself is not a disinfectant. It may be used in hot tubs because when combined with silver ions as in the Nature2 system and at hot temperatures the combination can disinfect and has passed EPA tests. It's much more expensive than bleach, but its main advantage in a spa is that it lasts longer than chlorine so if you aren't soaking every day or two you can go a week without having to dose, even if you have an ozonator (with an ozonator, the ozone reacts with chlorine depleting it faster). That is, you dose after your soak, but don't usually need to dose again until after your next soak. With chlorine, you generally have to dose every day or two, especially if you have an ozonator.
Are you treating this as a pool or a spa? Is there a UV system or an ozonator? Got it from your signature. Use liquid chlorine for your slam.