Waves are waves. Whether it's surface movement or a bazillion little shakes of the sample container.
That's not to say it has to be different when it gets to the store, but there's no guarantee it's not compromised.
You can also skew it by letting the sample warm up first. For example, it sits on the counter for an hour and then warms up further in the car. You're getting a good reading of the sample, but the pool is X.X and the sample may be X.Y or Y.Y. if it's orange or purple it's easy to see. People split hairs on what shade of pink it is when 7.4 to 7.6 doesn't change the price of beer. Maybe it was 7.5 and both are close enough.
That's not to say it has to be different when it gets to the store, but there's no guarantee it's not compromised.
You can also skew it by letting the sample warm up first. For example, it sits on the counter for an hour and then warms up further in the car. You're getting a good reading of the sample, but the pool is X.X and the sample may be X.Y or Y.Y. if it's orange or purple it's easy to see. People split hairs on what shade of pink it is when 7.4 to 7.6 doesn't change the price of beer. Maybe it was 7.5 and both are close enough.