If the CYA has dropped by a lot and you are getting CCs and the pH and TA are going down when you add liquid chlorine, then you probably have ammonia.
Why Does pH drop When Treating Ammonia With Liquid Chlorine?
Oxidizing ammonia creates acid by releasing hydrogen.
More than 95% of ammonia is in the form of the ammonium ion (NH4
+)
4NH
4+ + 3HOCl + 3OCl
- --> 2N
2 + 6H
2O + 7H
+ +6Cl
-
When adding 12.5% sodium hypochlorite (liquid chlorine) to a pool to oxidize ammonia, every gallon of liquid chlorine will create the equivalent of 15 ounces of 31.45% hydrochloric acid.
10 gallons of 12.5% liquid chlorine added to 25,000 gallons of pool water with ammonia will lower the TA by about 23 ppm or the equivalent of adding 150 ounces of full strength 31.45% muriatic acid.
Every 8.53 gallons of 12.5% liquid chlorine is equivalent to about 1 gallon of 31.45% acid.
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