It usually is this green every opening. I have always just sanitized and vac to waste seemed to work then. I have about half of it drained now but I am so paranoid about the water table here. I'm sure it is fine but I'll always have that concern. I dug a 4 foot deep hole last year and didn't hit water... but my pool is 6 ft deep at the deep end.
If there is any question about the water table, don't roll the dice. Below is what I would do, but might want to get a couple opinions...
Biggest concern is your CSI on the gunite.
You are OK right now, because your high pH is keeping your CSI in the safe zone. But, if you start lowering it before increasing your CH and TA, it will be out of the safe zone.
So, first fill your pool, then retest your water. Depending on what your fill water looks like (if it's very hard), that in itself may address the issues.
Add CYA to get it to about 40.
I would take your CH to about 250. That's a bit on the low side... But, it's easy to overshoot CH (I've done it myself). And, once you overshoot, it sucks to take it back down.
Take your TA to 90. A bit on the high side. But, when you knock down your pH, it's going to knock down your TA. And, it will help with the initial CSI.
Then bring down your pH to about 7.2. (I think your CSI should be OK with any pH in the 7's).
Then, start your SLAM.