I don't see a good expansion joint. The expansion joint should be about 1/4" to 3/8" and very uniform. The expansion joint needs to be filled with a good expansion joint caulk.
In my opinion, the expansion joint needs to be saw cut and done correctly to allow the deck to expand and contract without pushing on the coping.
The buckling looks like it is due to horizontal expansion of the coping stones. It looks like one coping to the left of the skimmer is cracked. If the stones were grouted when they were cold, they would be at minimum width. When they heat up and expand, there is nowhere to go. The grout should be done when the coping is hot and fully expanded. That way the grout would tend to separate in hairline cracks instead of compression problems like you are seeing.
In addition to saw cutting the entire expansion joint, I would suggest that you do some thin relief cuts at the grout joints and regrout when the coping is hot. Do this right before the weather starts to warm up and then grout on a hot day.
Check all of the stones by tapping lightly with the plastic end of a screwdriver to see which stones sound hollow. The hollow ones are unbonded and need to be taken up and reset.