2 different pool stores couldn't figure out my "nitrate problem".
If anyone tells you that nitrates somehow react with chlorine, ask them how.
Nitrogen has two electron shells. One shell has two electrons and the outer “Valence” shell can have up to 8 electrons. The nitrogen atom has 7 protons. So, the oxidation state is determined by how many total electrons there are.
The atom only gains or loses electrons from the outer shell. If the outer shell is full with 8 electrons, the oxidation state is -8 + -2 + 7 = -3. This is the case with ammonia.
If the outer shell is empty, the oxidation state is 0 + -2 + 7 = +5. In nitrate, the outer shell is empty and there are no electrons for chlorine to take. So, chlorine cannot react with nitrate.
In addition, even if chlorine could react with nitrate (which it can’t), the nitrate would eventually get depleted. This is what happens with ammonia where the chlorine does react with the ammonia, but the ammonia gets depleted by the reaction and it eventually goes to zero.
Nitrates and phosphates can make the water more reactive to algae. So, you have to be vigilant about maintaining the chlorine at the proper level at all time. As long as you do this, you should be fine.