Hi quick question. By this do you mean you do 5ml pool water and 5 ml distilled water? Or 10ml and 10ml?Use a 10 ml sample. Each drop of R0012 to blue is 25 ppm CH. A SpeedStir really helps.
I suggest you follow the metals interference process described in Calcium Hardness
Another option is to cut the pool water 1:1 with Distilled Water. Then use that mix for the 10 ml sample. Do the test and double the results.