Welcome to TFP! :wave: Are you on a well? Try the following DIY tests:
1 - Vitamin C tablets - iron
2 - Rub a chlorine tablet on the stain, but don't leave it on one spot - organic
3 - Put some dry acid (i.e. pH Down) in a sock and rub the area - copper.

Also post a full set of water test results and tell us what chemicals may have been added to the water since it was filled if you know them.
 
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