orinokai

Member
Nov 29, 2022
11
Cornwall, UK
I wanted to share a success story after purchasing a larch wood-fired hot tub and finally finding a way to maintain the water successfully!

When I originally planned to buy the tub, I received a lot of advice warning me that wood hot tubs are notoriously difficult to maintain because wood is a delicate material that is easily damaged by oxidisers and can also destabilise your water chemistry due to tannins and other organic compounds. I was nearly put off, but stubbornly decided to give it a go.

The tub manufacturer advised against using chlorine and instead recommended an (expensive) MPS product with silver ions. I wasn't convinced about the efficacy of the product (especially when the tub water was cold) and a comment on this site encouraged me to try a low but consistent level of chlorine instead. I used dichlor granules and this kept the water in good condition for a couple of weeks at a time, but after that the combined chlorine levels started to rise. I wasn't comfortable shocking the water because of the potential damage to the wood, so I ended up changing the water pretty regularly.

After a while this started to get a bit tedious, so I invested in a UV light and sand filter that I run on a timer twice a day for 2 hours. I've been doing this for about a year now (while continuing to maintain FC at 1-3ppm) and it seems to be working very well. The wood is in great condition, the water is clear and sanitary (i do regular bacteria tests) and algae/mould seems under control (i change the water every couple of months and give the walls a quick soapy scrub too). I only use the tub every 2-3 weeks, so this method is perfect because I only need to check the levels every 4-5 days and it doesn't feel like too much work.

I hope this is of interest to anyone who might be considering a wood tub or currently struggling to maintain one.
 
Great to hear about a wood tub success story. Many people love to get them but they often turn into nightmare stories.

Are you keeping the CYA in check? With the dichlor constantly adding CYA, the active chlorine levels drop with rising CYA and so the kill rates go down. It has the beneficial effect of keeping the oxidizer level low which is good for the wood surfaces but bad for sanitation.

I wonder if you’d be willing to try adding dichlor up to 20-30ppm CYA and then switch to liquid chlorine only plus your standard UV regimen. Just curious to see if you can maintain the tub water longer.
 
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I agree with @JoyfulNoise. High cya is the likely issue.
There is a UV/H2O2 (hydrogen peroxide) system that has been very successful in my experience. Popular in Boulder, or used to be anyway. You might check that out too. I've read a study that suggest that certain wavelengths of UV generate H2O2 in water just as they generate ozone in air, so a UV system is already an H2O2 system. I'm not sciencey (is that a word?) enough to say myself, but it was an interesting read.
I am curious if your UV is also an ozone generator?
 
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I agree with @JoyfulNoise. High cya is the likely issue.
There is a UV/H2O2 (hydrogen peroxide) system that has been very successful in my experience. Popular in Boulder, or used to be anyway. You might check that out too. I've read a study that suggest that certain wavelengths of UV generate H2O2 in water just as they generate ozone in air, so a UV system is already an H2O2 system. I'm not sciencey (is that a word?) enough to say myself, but it was an interesting read.
I am curious if your UV is also an ozone generator?

UV light generates chemical compounds called free radicals. You might have heard that term used in biochemistry as free radicals in the human body are produced by stress and disease and can cause cellular death. The human body has multiple different means of destroying free radicals to protect cells against oxidative stress.

Free radicals, typically hydroxyl radicals (OH• … the dot is the symbol for a radical in chemistry, older text will use an asterisk), can be generated by UV light and are very powerful oxidizers. But they have incredibly short lifetimes, some types only exist for nanoseconds in solution. One chemical pathway for the breakdown of hydroxyl radicals is to form peroxide molecules. So, as you can guess, radicals are so powerful that they can create an oxidizer like peroxide which, in and of itself, is a very potent oxidizer. There are also chemical reactions called Fenton Reactions in which peroxide in conjunction with ferric ions (Fe2+) can cause the generation of hydroxyl radicals in larger quantities. Fenton reactions are used in water treatment to destroy some of the most difficult to oxidize organic compounds like the fluorinated hydrocarbons PFOS.
 
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