You can try putting some sort of descaler solution into the anchor cups to break the bond.
Note: Acid can be dangerous and it can squirt out in some cases if you use force.
Wear eye protection if you use any type of descaler solution.
Be careful to prevent a situation where the solution can be forced out of the cups under pressure like if you put descaler in the cups and then try to rotate the rails to break them loose.
Maybe wrap a towel around the base of the rail at the cup to prevent descaler solution from squirting out.
If you use an acid based descaler, it might damage the anchor cups.
Aluminum will be damaged much more than brass, so be extra careful if the cups are aluminum.
Can you tell if the cups are aluminum or brass?
Note: Acid can be dangerous and it can squirt out in some cases if you use force.
Wear eye protection if you use any type of descaler solution.
Be careful to prevent a situation where the solution can be forced out of the cups under pressure like if you put descaler in the cups and then try to rotate the rails to break them loose.
Maybe wrap a towel around the base of the rail at the cup to prevent descaler solution from squirting out.
If you use an acid based descaler, it might damage the anchor cups.
Aluminum will be damaged much more than brass, so be extra careful if the cups are aluminum.
Can you tell if the cups are aluminum or brass?

Hercules Haymaker Tankless Water Heater Descaler 35230 - The Home Depot
Hercules Haymaker Tankless Water Heater Descaler quickly and easily dissolves inorganic deposits that restrict flow to restore circulation and heat transfer efficiency. It's safe for potable water systems
www.homedepot.com

Durgol Universal Clear Multi-Purpose Descaler/Decalcifier (2-Pack) 0296-2 - The Home Depot
Serve your guests, family, or just yourself the perfect cup of coffee with the selection of this Durgol Universal Clear MultiPurpose Descaler Decalcifier.
www.homedepot.com
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