Featured Pool Chemistry, stainless steel corrosion and prevention, long term study.

PoolStored

TFP Expert
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Jun 24, 2021
16,869
Ashtabula, OH
Pool Size
29000
Surface
Vinyl
Chlorine
Salt Water Generator
SWG Type
CircuPool RJ-60 Plus
this may take a year or two to see if there is a case for this type of corrosion control.

Backstory: Bought house with a pool in 2020. In June 2022, I bought a new ladder, because there was a little bit of rusting, so I bought a 316 SS Marine Grade ladder and installed. I bounced along with TFP care, pool has been great.

Fast forward to 2023 and 2024, and I started getting rusting and pitting on the ladder. In the June of 2024, my heater went out (Raypak Heater leaking. Rebuild thread.).

The rust and the heater led me to evaluate everything. After much contemplation, I concluded two things.
  • Running my VSP slow did not provide enough flow to properly run the heater, leading to overheating. To protect the new heater, I installed a flow meter to ensure I had enough flow for the new heater to protect it . I also added a flow switch in series with the pressure switch on the heater, so insufficient flow will shut down heater (pound of prevention and all.... (see my post above for details).
  • Something was up chemically, as @1poolman1 described in his assessment of the heater, and my post inspection, is that the heat exchanger had corroded.
My pool math logs are open to anyone. If you looked at 2022 and 2023, you would say they are fine. You might comment on my negative CSI, but CSI is an indication of “corrosion/etching” or scaling towards calcium carbonate, not metals. We have long established TFP advice telling people to ignore low CSI in a vinyl liner as we don't have plaster/grout. ( Negative CSI and metal corrosion )

Now that we eliminated CSI from helping, the next advice we provide is “keep your pH >7.” My pH was typically 7.4 during this time, so “couldn’t be pH.” We all know that low pH <7.0 can corrode metals, but is that enough? Maybe not. Luckily there are indexes that provide insight into potential for corrosion to metals. Ryznar (RI) (thanks @JoyfulNoise) and others. An RI of 6-7 is little corrosion, 7-7.5 is significant corrosion, 7-9 there is heavy corrosion.

When I run my RI numbers for 2022/3, with pH of 7.4, TDS of 3045, CA2+ of 50, and HCO3- of 60, and a water temp of 84 Degrees F, my RI was 9.4. Yikes.

What is going on with my chemistry, how’d I get there and what can I do differently?

Looking at the index, we have pH, TDS (mostly salt in my pool), Calcium ions, and bicarbonate (TA). pH has a big influence on the index, TDS, Calcium and bicarbonate has some influence on the index. I decided to use Borates when I installed the salt cell to lower pH in the cell and keep the plates clean (works great). However, Borates lowers pH when added; I had a pH of 7.6 when I added borates, which lowered my pH to 7.4. I ran a TA of 60. I also use a cover. With a TA of 60 and a solar cover, pH just sat at 7.4. Never had a thought about raising pH…why would I?, when pH was stable. Calcium is also not necessary in a vinyl pool right? I just never worried about it. Now I do, and my pH and TA.

So with new heater, I changed my approach...
  • I run my TA at 80 (which also matches my fill water luckily), so I just don’t worry about TA anymore. This helped my RI a bit.
  • I run my pH at 7.8, with is just fine with a TA of 80. With the cover, I add acid twice a year, maybe.
  • I run my Calcium at 300 to start the year, with all our rain, and backwash, I end up about 200-250 by the end of the year. Having the calcium also helps protect the copper in the gas heater. ( Calcium Hardness - Further Reading )
So what did that do to my RI? Great question! RI lowered to 7.7. Still in the corrosion range. Interestingly, even if I reverted to a chlorine pool with a TDS of 500-1000, RI would only go down to 7.3, so corrosion is going to happen in a pool. Adding running at 8.0 pH RI only goes down to 7.1. On top of all that, I could run my CH up to 500 and get RI down to 6.6. Buuuut, my CSI goes to +.22. Am I willing to test going up to .2 CSI and see if borates at 60 can keep the cell clean? No, silly. That would mean water exchange and a cell cleaning if it failed, so not trouble free. I'll stick with my "lower" RI of 7.7 and see what happens...for now, not ruling out the test (no comments @Newdude ). I don't think there is a way to avoid SS corrosion in a pool.

We had a thread this spring that brought me back to the ladders...what am I going to do?, they are fugly. ( Rust on hand rail at water line ). I did my investigation and put together a plan, and wrote up wiki content. (Corrosion - Further Reading) and (Salt - Further Reading)

Sooooo, my next plan of attack is prevention, namely putting a barrier on the stainless. I pulled out the old ladders, which were not as bad as I remembered (old right, new left):
IMG_2139.jpeg

The plan:
Read the wiki on the causes and protection, but the plan is to remove the rust, passivating (removing surface contaminants like iron particles and restoring the protective chromium oxide later on stainless steel), then sealing the metal. I'm going to use naval jelly for removal, Teknikem CitriSurf 77 Plus for passivating, Everbrite for a sealer. The sealer will protect the SS from the water. There may be some issues at mating surfaces that scratch the Everbrite, but it is worth a shot. Also not in the wiki, but entirely possible is that the "splash zone effect" in the wiki is the cause for the waterline rust, the below the waterline rust may be that the bolts are a different metal than the stairs and tube causing galvanic corrosion on steps below the waterline. I have not been able to source 316 marine grade bolts...the ones that were used are advertised as such by SR. Smith.

NOTE: Everbrite recommends a 2 week cure period before submerging in water. Plan ahead.

IMG_2146.jpeg

First Phase, rust removal Before (notice the step above the waterline with no corrosion:

IMG_2140.jpeg

IMG_2142.jpeg


After:
IMG_2143.jpeg
IMG_2144.jpeg
IMG_2145.jpeg

Next up? Passivating and sealing...for another day!

Give me your best shot @JoyfulNoise I got nothing better...:laughblue: 😲 :laughblue: 😲

(side note, if you want to run your own numbers, use your pH, consult the “Draining” wiki to calculate your TDS, for calcium ions take your CH and multiply by .4, and for bicarbonate, just use your TA, and the RI calculator here: ryznar stability index )
 
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The moral of the story is there is no chemical mix that will protect all materials in a pool.

You have to decide which you protect and which you will sacrifice.

A pool is a depreciating asset with consumables.
 
The moral of the story is there is no chemical mix that will protect all materials in a pool.

You have to decide which you protect and which you will sacrifice.

A pool is a depreciating asset with consumables.
Absolutely Spot On!!! Preach!
 
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Your ladder may have been 316L … but what were the fasteners made of? Can you confirm that the nuts and bolts were 316L?

Also, is the ladder properly bonded at the deck cups?

Finally, no chemicals are added to the pool near the ladder, correct?
 
the below the waterline rust may be that the bolts are a different metal than the stairs and tube causing galvanic corrosion on steps below the waterline

but what were the fasteners made of? Can you confirm that the nuts and bolts were 316L?
No, I cannot confirm. SR Smith represents that the bolts with the 316 ladder are 316L. I don't believe it.

Also, is the ladder properly bonded at the deck cups?
Ha Ha, no way. They are likely aluminum flanged adaptors that I'm replacing. The bolts are galvanized lag bolts and the expanders are probably lead. Galvanic Soup!!!

IMG_2148.jpeg
Also, is the ladder properly bonded at the deck cups?

Finally, no chemicals are added to the pool near the ladder, correct?
There is likely no bonding to the expanders, adaptors or ladder.
No chemicals added to the ladder area...

At this point, with MY pool and ladder I consider the adapters and ladder to be consumables...which I *may* be able to extend the life with some protection. Interesting experiment...for me. YMMV.
 
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You could try bolting a magnesium anode to some part of the ladder and see if that helps. It’ll dissolve into the pool water if there’s any galvanic current. Won’t hurt anything.

Also, crevice corrosion and pitting corrosion happen without any galvanic couples. Once the passivation is compromised on the steel surface by any kind of mechanical damage … like bolts scraping against it … there will be corrosion as the Fe2+/Fe3+ redox reactions can happen in the absence of any external galvanic couple.

Sorry, steel is a pain. Maybe see if you can find an all brass ladder and then paint it with the zinc and lead based paints that the Navy coats every exposed component of their ships with …. it’s only harmful if you ingest the chips … or stand kind of close to the paint … or breath any of the air that surrounds them …

go cartoons no GIF by Cartoon Hangover
 
Interesting hypothesis. And who doesn't love making long formulas in spreadsheets? (Well, I like it!)

Does actual Salt (NaCl) content need to be taken into account? The 'Draining" wiki didn't mention it.

Since my last serious chemistry class was in 1968 (!), I am in no way equipped to debate any points.

But I will, anyway - playing with the numbers, even with my changing chemistries over the decades, my water has always fallen into the "aggressive" range. Yet it took my base model Raypak heater about 25 yrs to give up the ghost, and not from the core either. And my stainless ladder is now 33 yrs old. Granted, each had 1/2 of each year with no pool water in or on them (winter, ya know).
One would think that there would be a gigantic number of "my this or that is failing/ruined after only X time" posts over the years.

So, as others above have mentioned, there are other things in play here too. Quality of materials in the past vs now, bonding, anodes (if anyone practices witchcraft), and other items I am not ignorant enough about to claim are factors.

I'll let my betters continue the discussion. Always up for more learning about a subject!

Thanks for posting!
 

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@JoyfulNoise I passed this out of hand without thinking about it. For some reason my head went to "I'd have to run a wire across my deck." (it was late, lol)

I certainly could do that with one of the stair bolts, do you have a recommendation of something that might work?

What about this around one of the tubes?


There are lots of different shapes out there and even magnesium anodes that have copper wires cast into them so they can be buried in soil and discretely attached. But yeah, that one that attaches to a tube looks promising. Make sure you weigh it first so you know the starting point. Then maybe pull it at the end of the season to see if its weight changed. Any weight change is directly proportional to the impressed galvanic current at the ladder.
 
@JoyfulNoise I passed this out of hand without thinking about it. For some reason my head went to "I'd have to run a wire across my deck." (it was late, lol)

I certainly could do that with one of the stair bolts, do you have a recommendation of something that might work?

What about this around one of the tubes?
The description states “ Not recommended for Use in salt or brackish water”
Does that apply to a pool salt level that is 10% of an oceans?
 

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