Pool Water Conservation

onBalance

TFP Expert
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In The Industry
Jul 25, 2011
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Utah
POOL WATER CONSERVATION

Water conservation has been in the spotlight as the result of drought conditions affecting various parts of the country from year to year. In an effort to be responsible in the conservation of this valuable resource, onBalance has been investigating various ways the pool and spa industry can help reduce unnecessary water loss.

In the water chemistry standard, it is recommended that pools be drained if the
• Total Dissolved Solids (TDS) exceeds 1500 ppm over the starting point, if the
• Total Calcium hardness (TC) exceeds 1000 ppm, or if the
• Cyanuric Acid (CyA) exceeds 100 ppm.

Focus on the target – One way the pool industry could point our members toward conservation would be to change the primary recommendation from “drain the pool” to “lower the concentration” of the out-of-range constituent in the water. This would focus the operator on the fact that there are often other legitimate alternatives to draining. As applicable, these alternatives could then be listed.
Total Dissolved Solids – In the early 1990s we beta tested and then purchased and operated what may have been the first reverse osmosis/nanofilter purpose-built for the pool industry, and reported on our results in the trade press in 1993 and in the Journal of the Swimming Pool and Spa Industry in 1995.

This alternative to draining a pool filters to the nano- rather than the micro-level. Although as much as 10% of the water may be lost (rejected as brine) in the process, the other 90% can be softened to recommended levels. In addition to TDS, metals, minerals, salts, disinfection byproducts and other undesirable solubilized compounds are also removed.

Calcium Hardness – Another way of reducing calcium hardness in pool water (in addition to nanofiltration) is to precipitate the calcium by “dumping” sodium carbonate (soda ash) in the pool, and then filtering out the resultant calcium carbonate precipitate using a DE filter. This “lime softening” process is capable of lowering calcium hardness down to about the 300-400 ppm level while slightly lowering the pH and alkalinity.
(see Education – Pool Help and How to Fix 'Milky' Pool Water (Without Draining) for more information) This process only removes calcium hardness, not TDS.

Cyanuric Acid – There are also methods to remove cyanuric acid from pool water without draining a pool. These methods include nanofiltration, polymer skimmer pillows and activated organism additives. onBalance has also been successful removing cyanuric acid in our demo pools using alum flocking, melamine complexing and hyperchlorination (see Research Update: CYA Removal Method Confirmed and the poolhelp link above). Our industry does not need to endorse or even recommend any of these methods. However, we can and should recommend cyanuric acid reduction. We can then inform the operator that draining, nanofiltration, or the various other chemical applications are available to lower the cyanuric acid concentration.

It is our hope that a mention of alternatives to draining for calcium hardness and cyanuric acid buildup will inform service techs, operators, pool owners and regulatory entities that there are viable methods of lowering these soluble compounds while respecting water usage and conservation at the same time.
 
Lime softening traditionally uses “lime water” (CaOH2 … not the little green citrus fruit) to cause calcium and magnesium precipitation. One also adds a necessary amount of sodium carbonate to provide the carbonate ions to cause precipitation of calcite. The only issue is that the pH can rise quite a bit where it would need to be corrected with acid additions. The result is that the water decreases in CH but typically becomes more saline from the sodium chloride formed. This would also be problematic in a plaster pool as there is no way to control precipitation and the calcite formation could nucleate on the pool walls causing very bad scaling. It may really only be. A viable option for vinyl or fiberglass pools.
 
Lime softening traditionally uses “lime water” (CaOH2 … not the little green citrus fruit) to cause calcium and magnesium precipitation. One also adds a necessary amount of sodium carbonate to provide the carbonate ions to cause precipitation of calcite. The only issue is that the pH can rise quite a bit where it would need to be corrected with acid additions. The result is that the water decreases in CH but typically becomes more saline from the sodium chloride formed. This would also be problematic in a plaster pool as there is no way to control precipitation and the calcite formation could nucleate on the pool walls causing very bad scaling. It may really only be. A viable option for vinyl or fiberglass pools.
This is the priceless content I support this for. Plus also a great pool experience.
 
In response to @JoyfulNoise comments.
About the pH rising: If enough soda is added to cause the wholesale precipitation of calcium carbonate, then there is no rising of the pH, nor the alkalinity, and therefore, no acid adjustments are needed. (At least that has been our experience).

About the sodium chloride increasing: It is true that the sodium content increases while the calcium level decreases, but I don't see how the chloride content would increase.

About calcite nucleating and sticking on plaster pool walls. Yes, that is very possible. However, in the few times we have performed this procedure, hard calcium crystals have not stuck on the plaster pool walls. A few service techs have told us that they didn't have that problem either. Just in case, I would always suggest a strong brushing of the pool when/if this procedure is performed.
 
Perhaps you can post the exact details of the lime softening process your technicians used? There are several different variations of it that both use or exclude sodium carbonate as an additive. It depends on what you are trying precipitate, if other hardness ions are present (like magnesium) or if there is non-carbonate anions as well (sulfates). Typical lime softening processes leave behind considerable amounts of sludge as well as water with a pH near 10 due to the caustic nature of lime.
 
Calcium Hardness – Another way of reducing calcium hardness in pool water (in addition to nanofiltration) is to precipitate the calcium by “dumping” sodium carbonate

Why is this done in the pool, rather than using a seperate small 2nd hand above ground pool as a processing tank? Then use a fine drinking water filter to transfer each batch back into main pool. Or use an adaptive to get the particle to drop to bottom of the processing tank.
 
Water drained from a pool does not 'waste' the water. It returns to the environment and is reused. Either through direct water reclamation or evaporation.
 
We kept this experiment simple and only used soda ash (sodium carbonate) to precipitate calcium and then filtered it out. We have not tried using lime (calcium hydroxide)..... yet. But of course, we are certain that using lime would work very well. In fact, we believe it would probably precipitate out magnesium as magnesium hydroxide or magnesium carbonate.
In thinking about this experiment, I now realize that we should have tested for possible magnesium reduction also. Fortunately, we are planning to do this procedure again on two pools this spring. So we will cover that aspect this time around.
 

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Why does it seem few pool owners have large rainwater collection tanks fed from their home roof used to dilute the pool over winter?
This is not common in the US but I have seen a few instances here. Most here who collect rainwater use it in their gardens and such.
Using a secondary pool or bladder for water pump out is also not common here in the states when doing pool resurfacing/liner changes etc. but I have seen it used “across the pond” quite a bit and think its a great idea!
 
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This link gives a good summary of lime softening used in potable water distribution systems.


Even though we don’t measure it commonly, pool water can have a significant magnesium content. Taylor sells a test kit that can measure both total hardness and calcium hardness. The difference between the two is typically from magnesium. Since pool water can contain sulfates and phosphates as well, it’s important to know what’s there so the right lime softening procedures can be used. Typically the final product has high pH (around 10 or so) and so some kind of adjustment is needed either using a mineral acid (muriatic acid) or carbon dioxide injection.