Hello JJ.
Girl you sound like you are on a roll. Keep up the great job. Chlorine can combine with other organics, other than algae, so hopefully the CC 1 was just the chlorine down there combining with the pine needles, and now that those are being removed problem solved.
As far as the TA being increased more, the recommended levels are merely a baseline and not everyone needs to go to that exact level to prevent their pH bounces, so you might want to just monitor it for a bit, and see if 70ppm TA helps the situation before raising it again.
A lot of people just allow their TA to float, and it will usually find it's own "sweet spot" and settle in, stopping all the crazy pH fluctuations which can be a pain for sure.
As far as the Polyquat containing chlorine it does not. I'm not sure if something that is in it (i.e. possibly the ethylene dichloride, or something else in it, may have registered as a false chlorine increase, but I can't say for certain, as that is way out of my level of knowledge. Perhaps someone more chemistry orientated than myself can better explain why it registered the way it did.
Polyquat may reduce the amount of chlorine needed to be added in a few cases, as mentioned in this link:
http://www.troublefreepool.com/threa...e-and-polyquat (Refer to comment #3)
and there are more cases where people have mentioned a significant decline in their chlorine levels after using PolyQuat. But as described by Jason in comment 3 in the link above, "most of the time it won't have any obvious effect on chlorine usage."
Here are a couple of links discussing this that might be of interest to you too.
http://www.troublefreepool.com/threads/46432-Polyquat-algaecides-Mode-of-Action
http://www.poolforum.com/pf2/showthread.php/6147-PolyQuat-and-Shocking-with-Chlorine
I hope this helps. Have a wonderful day.