Joe,
In theory, you can't use too much powder.. If you do, it should not make any difference.
That said, you want to try to use the same basic technique each time you test so that you can have faith in your results.
I generally try to test from about the same place every time.. You should not test if the pump has been off for several hours.. We normally recommend testing after the pump has been on for 30 minute or more.
If you are dosing once a day with Liquid Chlorine, then you should be testing just before dosing.. The whole point being that you want to make sure that your FC never drops below your minimum... I personally try to keep my FC at my target or higher.
Thanks,
Jim R.