I used Cover Free last year. Don't know if it helped or not, but I got the bottle for free. Natural Chemistry will push their 'phosphate free' aspect of the product if this matters to you. I don't worry about phosphates anymore. I didn't do any testing of the Cover Free, but prior years I used a fish of some sort that had a battery and electric pump in it - lasted a month. A friend in the same neighbourhood also owns a pool and was using a bubble cover. We did some comparisons and IIRC, overnigh temp loss for him was 1-3 celsius, while I was losing 5-7 - without the fish I was losing 10.
One thing about the Cover Free I noticed was that it was much thicker than the fish stuff. I left mine in a shed, which got pretty hot during the day, and I noticed it seemed to get even thicker in the heat and required a really good shaking to get it flowing out of the spout. If I use it this year, I might keep it inside the house.