Dark Stain on Plaster from Chlorine Puck

That's interesting. Trichlor typically bleaches out a finish, but that looks more like some sort of metal staining.

Do you use any kind of algaecide or added anything else to the pool we wouldn't typically recommend? Not looking to berate, just trying to help you figure out what caused it and whether there's a simple solution.
 
Nothing else added except a little acid every now and then to keep pH down.

Pre-pandemic I used bleach but it's become expensive and sometimes hard to locate. CYA level is a little low so I've been using pucks lately. Pool was originally filled by truck in 2016 but since then the level is maintained with rainwater. And, at least 1/3 of the water was pumped out and replaced with rainwater a couple years ago. The rainwater tank needed to be partially emptied for some maintenance so this was an opportunity to knock CH level down.
 
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