As this is a dry chemical, I just measure it in the same measuring cups, right?
Hi, Skenn81. I had to raise CH for the first time in a long while recently too, and I had the same question, plus I wondered how volume differs if you buy pellets or flakes. I bought 94% pure anhydrous CaCl pellets. The first time, I measured half as much as the pool calculator said in a convenient liquid measuring cup and pre-dissolved it in a very deep, thick bucket. I used the pool calculator to back into how much that volume of CaCl might have been expected to raise CH. The calculator predicted I would have gotten an increase of about 23% more than I actually got from the pellets.
After observing the exothermic reaction on my first addition, I thought I could probably get away with just expressing pellets over the deep end. I added about half as much the second time this way, not brushing it in. There was no measurable change in CH, but we got a lot of rain before I retested, and I'd been draining a bit and using rain to dilute CYA, which would also have diluted CH by some small amount. Still, that taught me that expressing and not brushing was probably a mistake.
My conclusion is that 1) measuring pellets in a liquid measuring cup will probably give you less CaCl than anticipated in the volume measure listed on the pool calculator, but since you want to start by adding too little and adjusting up as necessary anyway, that's not a problem, and 2) I safely got good results dissolving pellets in a large, thick bucket in plenty of water before adding near a jet in the deep end while the pool was running. If I had not had such a sturdy, deep bucket, expressing and brushing would seem the safer way to go given the heat produced by the reaction with water.