In comparison to the Taylor vial that comes with the Speed Stir, it seems that the vials that came with the TF-100 test kit (i.e. the blank vial and also the "Chlorine" vial) may be inaccurate. I filled a 10ml graduated cylinder with water for the test and emptied it into the TFTkit vial(s). Each one had the water line well below the 10mL line, meaning the top of the meniscus (albeit very hard to detect) was below the line. Refilling the graduated cylinder again to the 10mL mark and then pouring it into the Taylor vial put the bottom of the meniscus right on the 10mL mark. Furthermore, to flip the test around, I filled the TFTkit vial to the 10mL mark and poured its contents into the dry Taylor vial. The water went to the 11.5mL mark.
So what does this mean?
Well, if you're always filling the TFTkit vials to the same mark every time for every test, then there really isn't an issue as one test is relative to the next. However, the value of the FAS/DPD drop test, or other tests for that matter, may be inaccurate. For example, I performed two FAS/DPD tests, with one having exactly 10mL from the graduated cylinder and the other having the water-line/meniscus right on the vial's 10mL mark. The results were 33 drops vs. 37 drops, respectively. That's a difference of 2 PPM--pretty significant, no? Furthermore, one gave a drop's worth of CC's (the exact 10mL test) while the other did not.
Anyone else notice this?
Now...my graduated cylinder could be off, but not likely. It is a cheaper plastic one as opposed to a Pyrex piece. Despite this, it's still probably more accurate than the eyeball-looking-straight-on-the-vial technique. The plastic graduated cylinder gives that nice, "scientific" meniscus, as it should be. Overall, the meniscus was very pronounced in the graduated cylinder, and I would have no problem putting my confidence into the reading of "10mL."
Knowing this, I believe I may now get more accuracy with the CYA test. Now I can effectively measure out 15mL of water and R-013 rather than eyeball the vials.
Splitting hairs perhaps, but I thought I'd mention my findings.
So what does this mean?
Well, if you're always filling the TFTkit vials to the same mark every time for every test, then there really isn't an issue as one test is relative to the next. However, the value of the FAS/DPD drop test, or other tests for that matter, may be inaccurate. For example, I performed two FAS/DPD tests, with one having exactly 10mL from the graduated cylinder and the other having the water-line/meniscus right on the vial's 10mL mark. The results were 33 drops vs. 37 drops, respectively. That's a difference of 2 PPM--pretty significant, no? Furthermore, one gave a drop's worth of CC's (the exact 10mL test) while the other did not.
Anyone else notice this?
Now...my graduated cylinder could be off, but not likely. It is a cheaper plastic one as opposed to a Pyrex piece. Despite this, it's still probably more accurate than the eyeball-looking-straight-on-the-vial technique. The plastic graduated cylinder gives that nice, "scientific" meniscus, as it should be. Overall, the meniscus was very pronounced in the graduated cylinder, and I would have no problem putting my confidence into the reading of "10mL."
Knowing this, I believe I may now get more accuracy with the CYA test. Now I can effectively measure out 15mL of water and R-013 rather than eyeball the vials.
Splitting hairs perhaps, but I thought I'd mention my findings.