Phosphate Removal

Good morning, Cdchris -- the one I use has a 25 micron pre filter down to a 1 micron final: Pentek DGD-2501 Spun Polypropylene Filter Cartridge, 10 Scientific

In our tutorial on filters in pool school, the article cites "about 10 micron" for cartridge-style filters, so that would be my guess on the Pentair, Chris. If this is true, the extra fine filtering of either the slimebag in pool or pre filter on additions should assist with some of the iron.

Duraleigh...back in the deep-end phosphate threads this "no warranty" position of Pentair's and possibly Hayward's SWG was something I became aware of and talked to people in the industry about. Hayward's position is similar but less stringent in that if you test the cell at a tests center and it fails, they'll honor the warranty...but if it passes, you're on your own.

That's why I logged my experiment for much of the summer in terms of "was my cell producing FC dspite extremely high po4 levels? - Yes." In my case it did scale but it also shed the scale and didnt interfere with production.

Their rationale is the phenom at the engineering level is that a formula of ch + po4 + temp + ph --- at different variables, can cause po4 scaling on the cell plates and cause failure. Some authors at industry mags like Aqua have referred to the mfg levels as "not real world" -- a position that applied to Pentair.

But even though there is an Eng scenario behind the position on phosphates with the manufacturers, the customer service reps will instead say the same kind of nonsense/stuff pool stores do about algae food (I know...I argued with them about it at Hayward and eventually escalated the call to someone senior who then wrote to me that if I used a test center theoretically and it failed, they'd honor the warranty ;) )

So phosphate scaling can be a real thing, but the issue gets lost in the mythic-jazz-misinformation/spin about po4 as algae food...which as we know, doesn't matter in a TFP-level chlorinated pool.

But they can't actually say a predictive level because there are four variables to control for, (po4+ch+temp+ph) plus a fifth slippery one, which is rate of flow/use time. In boiler phosphate scale research, for example, continuous flow seems to reduce scaling.
 
Is this "phosphate warranty" written down anywhere? I couldn't find it on Pentair's website. Spoken words are not relevant.

Secondly, How have we determined that phosphates cause scale on these SWG plates? I have always learned that CALCIUM causes scale.
 
Its a developing area of research that flows, excuse the pun, from a lot of research going on in the boiler industry at the moment coupled with the increased municipal tendency to use HEDP sequestrants in water delivery.

There is calcium carbonate scale, which is more typical, and there is calcium phosphate scale, whch is independent of csi.

The latter is produced (inadvertently) via this formula published by Dow and previously referenced by ChemGeek:

http://msdssearch.dow.com/PublishedLiteratureDOWCOM/dh_0060/0901b803800602b8.pdf?filepath=/609-02023.pdf&fromPage=GetDoc

OnBalance dd some work on phosphate scaling in a commercial pool heater scenario in this article: The Case of the Mysterious Pool Deposits - AQUA Magazine

Pentair and others use the "water balance recommendations" method of warranty exclusion. In other words, Pentair now says po4 is recommended at x level, then uses that recc to void warranty.

For deep background on all types of scaling reactions (eg sulphates too) there is this excellent water industry paper posted by smallpooldad during hs struggles with high iron, phosphates and scaling: https://www.cedengineering.com/userfiles/Cooling%20Water%20Problems%20and%20Solutions.pdf

I've not read all 56 pages but sections helped me wrap my non-chemistry brain around the factors involved in different types of scale and extrapolate how it might work in my setting ;)
 
There is calcium carbonate scale, which is more typical, and there is calcium phosphate scale, whch is independent of csi.
So what percentage of scaling issues reported is phosphate scale? Is it 10%? Is it 1%? Is it more? How do we test for that potential? When do we know that phosphates will result in scale?

It seems to me we are chasing something out in the weeds that may (or may not) occur and then, only in the rarest of circumstances.

Secondly, I still don't find a written warranty by Pentaair or anyone else disavowing a warranty claim because of phosphates.......and if we ever find one, what will that limit be?

In short, I see no reason to continue the alarmist pool store mantra that phosphates are important to pool water management.
 
"Phosphates should not exceed 125 parts per billion (ppb)."

This is from the intellichlor owner's manual. It doesn't specifically say that the warranty is void if the phosphates are over 125 ppb, but one could imagine that they could potentially use it as a reason to not warranty a cell. However, I doubt that they would not cover a warranty claim unless they really felt that the phosphates did cause the problem.
 
"Phosphates should not exceed 125 parts per billion (ppb)."

This is from the intellichlor owner's manual. It doesn't specifically say that the warranty is void if the phosphates are over 125 ppb, but one could imagine that they could potentially use it as a reason to not warranty a cell. However, I doubt that they would not cover a warranty claim unless they really felt that the phosphates did cause the problem.

And this is on all Pentair Warranty Cards (see http://www.pentairpool.com/pdfs/LimitedWarrantyCard-2-16.pdf )

Exceptions that may result in denial of a warranty claim:
1. Damage caused by careless handling, improper repackaging, or shipping.
2. Damage due to misapplication, misuse, abuse or failure to operate equipment as specified in the owner’s manual.
3. Damage caused by failure to install products as specified in the owner’s manual.
4. Damage due to unauthorized product modifications or failure to use Pentair original replacement parts.
5. Damage caused by negligence, or failure to properly maintain products as specified in the owner’s manual.
6. Damage caused by failure to maintain water chemistry in conformity with the standards of the swimming pool industry for any length of time.
7. Damage caused by water freezing inside the product.
8. Accidental damage, fire, acts of God, or other circumstances outside the control of Pentair.

But I agree JamesW, it is more than likely Pentair would honor a warranty claim within the 3-year period unless there were some demonstrable gross negligence on the part of the pool owner.
 
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