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Has anyone used Bobe copper scuppers in their pool? Any issues with stained plaster in saltwater pools? Thank you

Our gunite/white plaster pool is less than 3 years old salt water pool. We have brown to grey staining. Had the pool acid washed then bleached. Mottling of plaster gone but the staining I described is still there. 2 different plaster companies have looked at it.....they have no idea what the...