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Hi everyone, Which should I remove first, copper or iron stains or does it matter? Thank you, D

Hi everyone, I have a 33k Gal, plaster pool using liquid chlorine. I just replaced enough pool water to get my CYA to 45. My FC is .6, CC .2, PH 7.6, TA 125, CH 350. The Pool Calculator said to add 2gal and 1cup of 12% chlorine to get my FC to 8. I plan on getting my FC between 6-8, then...