Cloudy green water after ascorbic acid treatment

May 9, 2018
4
Baton Rouge
Hi all, long time reader, first time poster.

I am in Baton Rouge, LA and use municipal water in an 18,000 gunite pool using chlorine with a newly installed cartridge filter. I use the BBB method on this site for pool chemistry.

I've had issues in the past with light yellow metal stains in the pool and I've successfully used the ascorbic acid treatment from posts on this site to get rid of them and re-opened the pool with no problem.

The stains have recollected slowly over the last year so I decided to do the ascrobic acid treatment again. The water was crystal clear blue, but the light stains had collected in the walls. With the pH at 6.8 and the chlorine zero'd out I added a little over 2lbs of ascorb to the pool and an hour later added 2 quarts Robelle 2550 mineral out stain remover (sequestrate). I added a Culator 4.0 ppm to the pump basket to prevent them from eventually recollecting.I let it circulate for 24 hours and the stains were all dissolved and looked great. The water was still clear blue.

I raised the ph to 7 and the alk was 90. I slowly began to add liquid chlorine bleach. The water has continued to circulate for 24 hours. The following day the water began to turn cloudy which I read was to be expected. However, when I checked the chlorine it was still zero. So i added more, slowly per the instructions and the water began to turn green. I read this could be due to metals so I added 1 more quart of sequestrate. The water has now been circulating for about 4 days straight and the water is still a cloudy light blue-green. It's not algae. The chlorine is still at zero, but the cloudyness and greenish-blue color has remained stubborn.

Any ideas? I haven't tested the water for the specific metal that, but suspect iron. I ordered some test strips today since its going on 5 days and it hasn't cleared up. I never had this issue with this process before and I have done it twice.

Currently the chemistry is ph 7.2, chlorine zero (keep slowly adding, I know the ascorb is likely eating it), alk 110, hardness 260, CYA 50-60.

Thanks!
 
did you say test strips? :pale:

I never did the ascorbic treatment because of that battle back with chlorine that others had discussed. A previous pool company used Metal Out by Pool Mate and I ordered this on Amazon. You can see the results and I never had that chlorine eating phenomenon.

I am sure some good folks will be through the help you out, but maybe you can cancel that test strip order and get yourself a test kit.
 

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I ordered some iron and copper test strips to see if I can figure out what/if any metal is in the pool. That Metal Out is the exact stuff I added after the treatment, although it's branded as Robelle Mineral Out.

I had been successful twice with the AA treatment to get the stains out but then never followed through with continuing the sequestrate and so they gradually reformed. But, I've never had problems with the pool turning a light-green or staying cloudy for this long after the treatment. I'm not sure if I should drop the pH and add more sequestrate, or continue to try and add chlorine. I'm at like 0.2-0.4ppm chlorine.
 
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Cloudy green, previously crystal clear blue. Frustrating!

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I'm not sure if its a problem with dissolved metals and not having enough sequestrate, although I've added 3 quarts which is enough for 30k gallons and my pool is only 18 gallons. It doesn't appear to be algae. There's none on the walls and the greenish blue color came very quickly after adding the chlorine. I would assume metals, but maybe I'll keep adding chlorine slowly and see if it gets better!
 
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