Ok first off you should use the 10 ml samples so each drop counts for .5 ppm FC not the 25 ml sample where each drop counts for .2 FC, this just makes you use up the limited amount of reagent in the K-2006 faster and .5 ppm resolution on FC is plenty.
You still need to get your FC down more, either a couple of more gallons of hydrogen peroxide or about 16 ounces of the thiosulfate then retest and then you should be low enough to get a valid pH reading.
Ike
p.s. did you buy the small cheaper K-2006 (K-2006a) or the larger commercial K-2006C? (check your expiration date, should be printed on the bottles, if not they are likely too old, Taylor started printing 24 month off expiration dates Jan of 2015) If the smaller you will probably need to reorder more reagents in couple of months.
Onces we get FC and pH lines up to sane levels we can address everything else
p.p.s. responding to your ps with FC over 10 your pH is still not entirely valid,