Okay, so about 2 hours after my last round, I saw almost no drop in FC and I tested the Ammonia and it's coming up zero. My CC was at 0.5, but I think that was just the last of the ammonia dying?
As suggested, I will wait another day and make sure that ammonia level is correct before I start adding CYA.
So for reference my issue was this:
CYA -0
FC- 0
Ammonia was roughly 4 ppm
It appears to have taken appx. 15 gallons of 12.5% liquid chlorine to kill all the ammonia in a 33,000 gallon pool.
My FC is now at 8.5.
My pH dropped from 7.5 to 6.8 with this massive chlorine addition.
I'll check the numbers again tomorrow and confirm this did it.
Thanks again for the assistance everyone.