Stain on bottom of pool

That's Calcium scale that has been tinted by metals and/or algae.

It won't lift easily or quickly. It can be dissolved by keeping the CSI slightly negative and brushing with a steel brush, but think glacially in terms of speed.

If you want it gone this year, you're looking at an acid wash or sandblasting.
 
+1 what 320 said.....both in terms of identification and solution.

My thinking is you have lived with it for some time so trying the slow approach (months) to getting rid of it might be your best bet.
 
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