Removing pool stains?

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Get some Vitamin C tablets. Put them in a thin sock/panty hose and crush them up a bit. Set it on the stain.
If it disappears, it is iron -- might be a wire tie or piece of rebar near the surface of the plaster.
I suggest you read ABC's of Pool Water Chemistry.
 
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If you can do it with the tablets that is easiest. To treat the entire pool, you do an AA treatment. Best done when the pool water is cold. The vitamin C eats chlorine, so watch your FC.
 
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