pH vs chlorine

goz63

Active member
Sep 28, 2019
30
Vancleave, MS
So I was reading a review on Amazon after I bought the Taylor salt test kit and they post said chlorine effectiveness goes down to like 20% with a pH of 8. Does a higher pH reduce the effectiveness of chlorine?
 

ajw22

Gold Supporter
TFP Guide
Jul 21, 2013
11,701
Northern NJ
Does Pool pH have an Effect on the Chlorine's Ability to Sanitize Water?

In a pool with zero CYA, chlorine is more effective at lower pH, but this relationship is much less with CYA in the water to point of being irrelevant.

pH does affect the active chlorine (hypochlorous acid) level that is responsible for most of the disinfection of the water. However, when Cyanuric Acid (CYA) is in the water, it buffers this active chlorine so that pH has far less of an effect on it.

To be specific, with no CYA in the water, going from a pH of 7.5 to 8.0 has the active chlorine level drop by 50%. With CYA in the water, it drops by only 15%. Going the other direction, going from a pH of 7.5 to 7.0 the active chlorine level with no CYA increases by a little more than 50% but with CYA in the water it increases by 35%.

So we generally ignore the pH effect on chlorine except for a SLAM because the larger amounts of chlorine have the pH rise significantly so we recommend lowering the pH first before a SLAM, especially when it's a lot of FC due to high CYA levels.