How do I use pool pump to drain

It's a direct ratio. If it really is 100 ppm then you need to drain 20% of the water to get to 80 ppm. I'd go a little more than that just to be safe.

So about 8,000 gallons. Or if your average pool depth is about 5 feet, you'd need to drain about 1 foot.
 
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How sure are you about the 100ppm CYA reading? How did you test it?

Realize that most good tests max out at 100ppm and you could be well above that.
 
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