Does Calcium Chloride Expire?

Calcium Chloride or Hardness Builder is a Basic/alkali with a pH around 7-8 depending on the product, so should be stored with your other alkalis - Bleach, Cal Hypo, Sodium Bi-Carb, Sodium Carbonate/soda ash.

Provided it is retained in an air-tight container which it is usually supplied in in sizes smaller than 25kg and in ambient temperature, there is if I recall correctly no shelf life.

Regards
Stuart
 
I doubt there is a limit. I had a 25lb. expensive pool-store bucket that sat half-full for years (at least five) while I used DowFlake in 50lb. bags. It was just fine when I eventually got around to using it (can't always find CaCl snow melt.) If exposed to air, it will absorb humidity and turn into a rock over time, but I bet it still would provide CH to your pool. You would just have to break it up.
 
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