Help 2nd year pebbletech with copper stain

Do you know the source of the copper in the water, and have you verified it is copper by checking it with a vitamin C tablet and water testing?
 
I do not know the source, however what are the usual suspects? I have pvc pipes, sand fileter, and 5 yr old hayward pump. I use clorine tablets and clorine shock. to balance the waeter I use tf-100 test kit. Where can I test my house water for copper? How do I use the Vit. C?
 
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