FPM, beat me...heres my take:
If stuff is sitting on the bottom, it needs to be stirred up for the filter to have a chance at it.
Until you are done with at least OCLT<1 ppm, and CC<0.5 ppm I would probably wait on the DE or floc. Once you pass those two tests, then I would try DE next, it can work wonders on a sand filter to clear the dead algae carcases. Lastly, if you want, you can try a floc at that point...realize the many flocs instruct to let the flocked debris fall to the bottom with the pump off for a number of hours, so if your not completely done killing the organics in your pool, you risk a comeback.