Ok, that test kit will do most of what you need, you can get just the FAS-DPD test and maybe the CYA only test kit from TF test kit, you don't need the whole TF-100 for now until you run out of supplies on the Leslies kit.
Chlorine free water is any source of water that has not had chlorine added, rain water, posssibly bottled water, distilled water, municipal tap water supplies usually have chlorine added which will throw off the test some. In reality when looking for this big of numbers even tap water is unlikely to throw it off much.
Ike