Painted pool - do I still need to add calcium?

I believe you have enough. Your pool is not really a masonry pool once you paint the masonry. I think it's still a pretty good idea to have some in there and you are not quite to what we suggest (250-400) for masonry pools but close enough for your situation.
 
Wouldn't the recommendation also depend on the age/condition of the paint? For example, we sometimes swim in a family member's pool - the pool is old, as is the OP's pool. The paint on the concrete is younger than the pool itself, but, judging by appearance, it's hard to believe the paint is providing much protection to the underlying concrete...
 
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