clorine puck stained my new plaster...

The chlorine concentration in the immediate area of the floater is very high. If it sits too long in one place, especially somewhere shallow, it can cause damage.

It is a bit of a long shot, but you might as well try holding a vitamin C tablet against the dark spot for 30 seconds and see if that improves the appearance around the tablet or not. High FC levels from the floater could have caused iron staining, which vitamin C tablets can remove.
 

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