(I wrote this while Jason posted above; some duplicate info here)
jt100 said:
My point is, it's not the ingredients that i know that concern me, it's the ingredients that i don't know that concern me a little.
For some pool chemicals, there are some differences between brands including the generics, but usually that is not the case.
Bleach and Chlorinating Liquid
Let's take bleach and chlorinating liquid, for example. 6% bleach is 6% sodium hypochlorite by weight and is 4.7% sodium chloride salt. [EDIT] For 8.25% bleach there is 8.25% sodium hypochlorite by weight and 6.5% sodium chloride salt. For 12.5% chlorinating liquid (where 12.5% is Trade %, not weight %) this is (assuming 1.16 g/ml density) 10.8% sodium hypochlorite by weight and 8.5% salt. [END-EDIT] This relationship comes from the manufacturing process (called "chlor-alkali") which creates chlorine gas and sodium hydroxide via electrolysis and then adds the chlorine gas to (purer) water containing sodium hydroxide. This is done in two steps as described in order to reduce the amount of salt in the water since the water used for initial electrolysis has very high salt content.
Cl
2(g) + 2NaOH ---> NaOCl + NaCl + H
2O
Chlorine Gas + Sodium Hydroxide ---> Sodium Hypochlorite + Sodium Chloride + Water
There is some excess sodium hydroxide (lye / caustic soda) leftover from the above process that varies by brand with Clorox Regular having around 0.063% by weight (using a pH of 11.9). Clorox adds a small amount of sodium polyacrylate (a polymer that prevents minerals in wash water from reacting with chlorine and yellowing the clothes) in an amount that they do not disclose but is probably very small by weight. The rest (88.7% for 6% bleach) is water. See
this link for info on Clorox Regular bleach.
Other brands of bleach often have more excess lye in them with some having a pH of 12.5 implying 0.25% by weight of sodium hydroxide. Other than this difference (and some bleaches not having sodium polyacrylate), they are all the same. There are also weaker bleaches where most off-brand Ultra bleaches are 6% but off-brand Regular are 3% or less. Bleach and chlorinating liquid are the same except for strength and differences in the amount of excess lye.
[EDIT] You do not want to use scented bleaches or specialty bleaches such as
Clorox® Outdoor Bleach or
Clorox® Splash-Less™ Bleach which have thickeners in it. [END-EDIT]
If you look at a bottle of 6% Clorox Regular unscented bleach, you will notice that it says "5.7% Available Chlorine" on the bottle in addition to the ingredients of "6% Sodium Hypochlorite". [EDIT] For 8.25% Clorox Regular Concentrated Bleach it says "Yields 7.85% Available Chlorine" on the bottle in addition to the ingredients of "Sodium Hypochlorite (8.25%)". [END-EDIT] This is because the product has been registered with the EPA not only as a pesticide, but has also been tested and approved for use in swimming pools. For 6% bleach, it has EPA registration number 5813-50 which is described in the
PAN database and has
this MSDS. [EDIT] For 8.25% bleach, it has EPA registration number 5813-100 which is described in the
PAN database and has
this MSDS. [END-EDIT] This process of testing and approval has little to do with the inert ingredients. It has to do with the efficacy of the product to kill bacteria as described in
EPA DIS/TSS-12. You can read a bulletin from Clorox on the use of their bleaches in swimming pools on pages 2-3 of
this document or pages 21-22 of
this document.
Baking Soda vs. Alkalinity Up
As described in
this link, "ARM & HAMMER
® Baking Soda is 100% pure sodium bicarbonate." It is also used in baking so is ingested in food. If anything, it is of even higher purity and quality than an Alkalinity Up product, all of which are sodium bicarbonate.
Washing Soda vs. pH Up
As described in
this link, "ARM & HAMMER
® Super Washing Soda is 100% pure sodium carbonate." [EDIT] However, according to
this MSDS (and
this info as well), the product is >= 85% sodium carbonate and <= 15% water. [END-EDIT] Many pH Up products are 100% sodium carbonate, though some are sodium sesquicarbonate which is a double salt of sodium bicarbonate and sodium carbonate, while a few are sodium bicarbonate.
Borax vs. Borate products
As described in
this link (click on the FAQ tab), "20 Mule Team
® Borax is comprised of 99.5% pure borax, a naturally occurring mineral composed of sodium, boron, oxygen, and water. (The scientific name for borax is sodium tetraborate decahydrate.) The remaining 0.5% is composed of trace minerals."
Products such as
ProTeam Supreme contain Sodium Tetraborate Pentahydrate which is the same as Borax except it contains less water (hydrates are chemicals that contain water including those in solid form in a crystal).
ProTeam Supreme Plus and
ProTeam Gentle Spa do not disclose their "Proprietary ingredient", but it is most surely Boric Acid given that the product overall has a pH of 6-8, that it increases borates, and that the product also contains some sodium tetraborate presumably to make the pH more neutral (boric acid is slightly acidic).
Muriatic Acid
This is diluted Hydrochloric Acid where full-strength is usually 31.45% (see
this MSDS) and half-strength around 15%-16%. There is no difference between brands and the inert ingredient is water.
Calcium Chloride vs. Calcium Hardness Increaser
Dowflake is around 96% Calcium Chloride Dihydrate.
This MSDS gives 77-80% Calcium Chloride, < 5% Sodium Chloride, 2-3% Potassium Chloride, 15-20% Water.
This MSDS gives some slightly different composition for this product (a little more calcium chloride content with less water).
Peladow as described
here is at least 91% Calcium Chloride Anhydrous with 4.5% Water, 2.5% Potassium Chloride, 1.5% Sodium Chloride.
This MSDS gives some slightly different composition for this product.
Hopefully this gives you some idea of how there really is no significant difference between grocery or big-box store vs. pool store chemicals, at least for the common ones used above and how their inert ingredients are truly not a problem.
Richard