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It is currently May 25th, 2012, 7:50 am
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bk406
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Post subject: Re: Phosphates can be a serious problem  Posted: October 18th, 2010, 10:27 am |
Joined: December 3rd, 2009, 11:28 am Posts: 2419 Location: Central Massachusetts
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teapot wrote: Not a witch hunt. And...with all due respect, this thread is over a year old. (Yes and I think you'll find I was there from the split off, on the other hand you only arrived to the post from Mike).The RO topic was brought up by you when you said "going off topic for a minute". (Yes off the topic of Mike) If you want to talk about RO, start another thread. (RO was a natural progression from Simicrintz mentioning his RO rig and what it can remove from water which is closer to the phosphate discussion than your vendetta against Mike.) No vendetta, just pointing out the obvious. Like I said, if you want to discuss RO, start a new thread. I cant move it or start a new one since I dont have the ability. Maybe a mod should move the RO discussion to it's own thread and close this one out.
_________________ 14,000 gallon IG, Vinyl. Hayward 3/4 hp superpump, Penatair IC40 SWCG, Pentair automation, Hayward sand filter, Aqua Comfort heat pump, Hayward 400k Lo-Nox LP heater.
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teapot
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Post subject: Re: Phosphates can be a serious problem  Posted: October 18th, 2010, 12:02 pm |
| In the Industry |
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Joined: July 25th, 2009, 5:29 am Posts: 580 Location: London and France
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No problem, if this starts to grow legs I will post a new thread, just a few questions for now though.
_________________ 24x12x5ft vinyl liner pool 12000 gallons. 24" sand filter with Dryden Aqua AFM (That's posh glass) 0.75hp pump, Waterco multi cyclone pre filter, Strantrol 3 controller, Seko pumps, ioniser and chlorine FAS DPD and Cyanuric acid tests kits available for Europe
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chem geek
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Post subject: Re: Phosphates can be a serious problem  Posted: October 18th, 2010, 2:45 pm |
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Joined: March 28th, 2007, 2:40 pm Posts: 5410 Location: San Rafael, CA USA
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teapot wrote: Do you know at what point CYA CH and phosphates are removed, 0.5 micron or finer still? Dissolved chemicals, such as CYA and calcium and carbonate ions, etc. have molecular sizes on the order of from 1 to 10 Angstroms. Even a 0.5 micron filter is 5000 Angstroms because 1 Angstrom is 0.1 nanometers. There are 10,000 microns in an Angstrom. Even a long-chain polymer like PolyQuat is on the order of 3000-5000 daltons (g/mole) molecular weight with a polymer structure shown here implying 12 to 20 units in the polymer so is maybe 250 Angstroms (0.025 microns) long and therefore would not get caught in an uncharged filter (however, PolyQuat is positively charged so would bind to a cationic exchange resin, for example). Reverse osmosis uses specialized membranes with extremely small pore sizes. It's quite different than regular filtration, requires substantial pressures, and is slow to filter unless membrane filter areas are extraordinarily large. Phosphates by themselves are ions in water so would not be removed by normal filtration, but would by RO. However, phosphates precipitated by adding lanthanum to form lanthanum phosphate can be readily filtered out as it forms precipitated solid particles (crystals). The water may remain milky for some time if a clarifier is not used as the precipitate is otherwise slow to consolidate.
Last edited by chem geek on October 18th, 2010, 7:55 pm, edited 4 times in total.
_________________ 16,000 gallon outdoor in-ground 16'x32' plaster pool; Pentair Intelliflo VF pump; Pentair IntelliTouch i9+3s control system; Jandy CL-340 square foot cartridge filter 12 Fafco solar panels; Purex Triton PowerMax 250 natural gas heater (200,000 BTU/hr output); automatic electric pool safety cover; 4-wheel pressure-side "The Pool Cleaner"
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teapot
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Post subject: Re: Phosphates can be a serious problem  Posted: October 18th, 2010, 3:26 pm |
| In the Industry |
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Joined: July 25th, 2009, 5:29 am Posts: 580 Location: London and France
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Thanks Richard, I found a chart earlier that helped with the size of various contaminants.
_________________ 24x12x5ft vinyl liner pool 12000 gallons. 24" sand filter with Dryden Aqua AFM (That's posh glass) 0.75hp pump, Waterco multi cyclone pre filter, Strantrol 3 controller, Seko pumps, ioniser and chlorine FAS DPD and Cyanuric acid tests kits available for Europe
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