Update:
OK, 5 more lbs of ascorbic acid and 5x32oz of Metal Hold added and not much change after 24hrs on re-circ.
pH was <6.8, Cl 0 and Al 40 beforehand.
3min of ascorbic in a sock against the stain did nothing, 30min began to lighten the stain, but not near what Jack's Stain ID kit did when...