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Should i shock it now and perform an overnight FC loss?
I wouldn't just yet. Why not try to determine what it is first? My assumption is the water is warm enough to get in. "pinch" some of the stuff that's settled between your thumb and forefinger. Algae, alive or dead, should be slippery and dirt should feel gritty.
If that's inconclusive, then I suggest an OCLT. Do you have the correct FAS/DPD test to perform it? If you are not clear on how to do it, reread or ask for help.
Then, if the OCLT indicates an excessive FC loss, it's time to shock your pool.
(I doubt this is related to your cleaner, but it is slightly possible)